Acid Base balance

You are called to a surgical ICU for consultation. A deteriorating patient (female, 67) has been treated for submassive pulmonary thrombembolism (following cervicocapital arthroplasty) with LMWH and oxygen given via nasal cannula. Blood pressure is maintained with combination of cathecholamines (norepinephrine + dobutamine). From the history: patient's been treated for hypertension, hyperlipidaemia, chronic renal failure and type II diabetes on insulin. Surgical senior house officer took blood samples for full blood count, ions and acid-base balance ("the Astrup method"). What type of blood sample is ideal for evaluation of the acid base balance in this scenario?
67
years
woman
RR
26 /min
HR
110 /min
SpO2
88 %
BP
100/54 (69) mmHg
temperature
37 °C
EKG
rythm: sinus
action: regular
frequency: 110 bpm
axis: 120°
pathol. SI, QIII, TIII, neg. T in V1-3
Examination
The patient is obese, lethargic, sub-febrile (37.2 °C), with acral cyanosis, GCS 11 and rapid shallow breathing. Capillary refill time is slightly prolonged (3s). Hands and feet are cold and dry. Diuresis is about 0.5 ml/kg/hr.
Glycaemia
Gly
6,0  mmol/L
Arterial blood gas
pH
7,4
pCO2
41,25  torr
pO2
97,5  torr
BE
0  mmol/l
Complete blood count
HGB
125  g/L
ERC
4  x1012/L
LEU
14  x109/L
PLT
250  x109/L
Biochemical analysis
Na
142  mmol/L
K
5,5  mmol/L
Cl
105  mmol/L
Ca
2,6  mmol/L
Glycaemia
Take a sample
Arterial blood gas
Take a sample
Complete blood count
Take a sample
Biochemical analysis
Take a sample